(in Polish) Chemia nieorganiczna 0600-S1-O-CNORG(II)
The course aims to discuss chemical properties and contemporary applications of the most important chemical elements and their compounds with an environmental and industrial perspective, to examine modern principles of electronic structure description (LCAO MO) and thermodynamical trends of redox processes, to relate the methods and techniques used for molecule structure determination.
Lecture
Origin and abundance of chemical elements in the Universe and the Earth, chemical evolution of Universe, periodic table of the elements, structure and electronic structure of chemical compounds, thermodynamics, chemical kinetics and mechanisms of redox, substitution and acid-base processes. Chemistry of the s, p, d and f blocks elements.
Chemistry (occurrence and abundance, applications, biological and environmental importance, synthesis, physicochemical properties, review of the essential compounds and reactions) of 1-2, 13-18 groups elements with special attention focused on the chemistry of hydrogen, boron, and aluminium, carbon and silicon, nitrogen and phosphorus, oxygen, sulfur, and chlorine. Coordination chemistry (main concepts, techniques) and review of properties, essential reactions, and applications of d-block elements.
Lanthanides and actinides - properties and contemporary uses of their compounds.
The course aims to discuss chemical properties and contemporary applications of the most important chemical elements and their compounds with an environmental and industrial perspective, to examine modern principles of electronic structure description (LCAO MO) and thermodynamical trends of redox processes, to relate the methods and techniques used for molecule structure determination.
Lecture
Origin and abundance of chemical elements in the Universe and the Earth, chemical evolution of Universe, periodic table of the elements, structure and electronic structure of chemical compounds, application of LCAO MO, application of Walsh-Mulliken diagrams to predict the structure, application of spectroscopic methods in structure determination, thermodynamics, chemical kinetics and mechanisms of redox, substitution and acid-base processes. Chemistry of the s, p, d and f blocks elements.
Chemistry (occurrence and abundance, applications, biological and environmental importance, synthesis, physicochemical properties, review of the essential compounds and reactions) of 1-2, 13-18 groups elements with special attention focused on the chemistry of hydrogen, boron, and aluminum, carbon and silicon, nitrogen and phosphorus, oxygen, sulfur, and chlorine. Coordination chemistry (main concepts, techniques) and review of properties, essential reactions, and applications of d-block elements.
Lanthanides and actinides - properties and contemporary uses of their compounds.
Organometallic chemistry selected topics.
Tutorials
Periodical table of the elements and their electronic structure, periodical changes of atomic properties of the elements: HOMO energy, electronegativity, chemical hardness, atomic volume, s-p orbitals energy gap changes, and their reasons. Nomenclature of inorganic and coordination compounds. Structure of covalent molecules, Lewis formulas, VSEPR.
Redox properties, Latimer, Frost, and Pourbaix diagrams, thermodynamic stability of the coordination compounds.
Laboratory
Synthesis, separation, purification, and determination of the composition of chemical compounds of the s and p block elements and coordination compounds of d block metals.
Application of electronic spectroscopy for identification of coordination compounds. Optical properties of coordination compounds.
Total student workload
Learning outcomes - knowledge
Learning outcomes - skills
Learning outcomes - social competencies
Teaching methods
Expository teaching methods
Exploratory teaching methods
- classic problem-solving
Prerequisites
Course coordinators
Assessment criteria
Written exam (65%), tutorials (15%), laboratory (20%).
Assessment criteria
< 50% unsatisfactory
50 - 60% sufficient
61 - 65% sufficient +
66 - 75% good
76 - 80% good +
> 80% very good
Written exam – W01, W02,W10, U01, U02, K01, K05.
Tests – W01, W02, W06, W10, U01, U02.
Activity – U17, K01, K04.
Laboratory work – W06, W10, W16, U01, U02, U10, U16, K01, K03, K06, K09.
Practical placement
Not applicable
Bibliography
Basic literature:
1. G.L. Miessler, P.J. Fisher, D.A. Tarr, Inorganic Chemistry, 5th ed., Pearson Education Inc. 2014.
2. P. Atkins, T. Overton, J. Rourke, M. Weller, F. Armstrong, Shriver & Atkins Inorganic Chemistry, 6th ed., W.H. Freeman and Company 2014;
3. C.E. Housecroft, A. G. Sharpe, Inorganic chemistry, 5th ed., Pearson 2018;
4. F.A. Cotton, G. Wilkinson, P.L. Gaus, Basic inorganic chemistry, John Wiley and Sons, Inc. 1987.
5. P.A. Cox, Instant Notes in Inorganic Chemistry, BIOS Scientific Publishers Ltd. 2000.
6. P. Kita, Inorganic Chemistry I – lectures, materiały dydaktyczne przygotowane do projektu pn. „Wzmocnienie potencjału dydaktycznego UMK w Toruniu w dziedzinach matematyczno-przyrodniczych” realizowanego w ramach Poddziałania 4.1.1. POKL, Toruń, 2011.
7. P. Kita, Inorganic Chemistry II – lectures, materiały dydaktyczne przygotowane do projektu pn. „Wzmocnienie potencjału dydaktycznego UMK w Toruniu w dziedzinach matematyczno-przyrodniczych” realizowanego w ramach Poddziałania 4.1.1. POKL, Toruń, 2015.
8. A. Katafias, A. Topolski, G. Wrzeszcz, J. Wiśniewska, Inorganic Chemistry – laboratory, materiały dydaktyczne przygotowane do projektu pn. „Wzmocnienie potencjału dydaktycznego UMK w Toruniu w dziedzinach matematyczno-przyrodniczych” realizowanego w ramach Poddziałania 4.1.1. POKL, Toruń, 2015.
9. P. Kita, Inorganic Chemistry I – tutorials, materiały dydaktyczne przygotowane do projektu pn. „Wzmocnienie potencjału dydaktycznego UMK w Toruniu w dziedzinach matematyczno-przyrodniczych” realizowanego w ramach Poddziałania 4.1.1. POKL, Toruń, 2011.
10. P. Kita, Inorganic Chemistry II – tutorials, materiały dydaktyczne przygotowane do projektu pn. „Wzmocnienie potencjału dydaktycznego UMK w Toruniu w dziedzinach matematyczno-przyrodniczych” realizowanego w ramach Poddziałania 4.1.1. POKL, Toruń, 2015.
Supplementary literature:
1. S.F.A. Kettle, Physical Inorganic Chemistrty: A Coordination Chemistry Approch, Oxford University Press 1998.
2. A.F. Wells, Strctural Inorganic Chemistry, 5th ed. Oxford University Press 1993.
Additional information
Additional information (registration calendar, class conductors, localization and schedules of classes), might be available in the USOSweb system: