Polymer chemistry 0600-S1-ChK-ChP

Lecture:
The lecture aims is the knowledge on the basic topics in the field of polymers and plastics. The types of polymers, chemical structure of macromolecules, degree of polymerization, average molecular weights and polydispersity of polymers, methods for the preparation and modification of polymers and mixtures and polymer composites will be discussed. The properties of polymers in solid state (including tacticty, conformation, II-order structure and glass transition temperature) and solutions will be presented. Solubility parameters, statistical coil, free volume, theta temperature will be determined. In addition, commercially available polymers and polymers with specific properties for special applications will be discussed.

Lab:
In laboratory practice, students will learn methods of studying the basic properties of polymers (determination of average molecular weights, solution viscosity, glass transition temperature, morphology, application of spectroscopy in polymer structure studies; mechanical properties; thermal, photochemical and biological stability). They get polymers by free radical polymerization and learn how to modify them.

Total student workload

1. 30h lecture, 60h lab, 30h consultation, ie 120 contact hours 2. 35h individual student work, 3. 45h time required for preparation in the assessment process, 4. total student workload - 200h.

Learning outcomes - knowledge

student: W1: can define and describe the basic types of polymers and copolymers - K_W08 W2: uses the correct terminology of macromolecular compounds - K_W08 W3: characterizes the properties of polymers in the solid state and in solution - K_W08 W4: describes the methods of obtaining polymers and their primary and secondary structures, as well as morphology - K_W06 W5: distinguishes linear, branched, cross-linked polymers, dendrimers, as well as copolymers with different arrangement of polymers in the chain - K_W08.

Learning outcomes - skills

student: U1: acquires practical skills in determining average molecular weights using viscometry, measures polymer viscosity in solution and calculates the limiting viscosity number - K_U03 U2: determines the glass transition temperature based on DSC measurements – K_U03 U3: predicts the reactivity and stability of polymers based on their chemical structure (presence of functional groups, branches, cross-links) and introduced admixtures (nanofillers, stabilizers, plasticizers) - K_U02 U4: can modify the polymer structure to obtain properties for special applications - K_U03 U5: performs simple syntheses using the free radical polymerization method and characterizes the physicochemical properties of the obtained polymers - K_U07 U6: correctly draws conclusions from the experiment - K_U03

Learning outcomes - social competencies

K1: demonstrates the ability to think analytically - K_K01 K2: is focused on completing the task as best as possible; pays attention to detail – K_K03 K3: works systematically and consistently - K_K06 K4: is focused on constantly acquiring knowledge, skills and experiences; sees the need for continuous improvement and improvement of professional competences - K_K05

Teaching methods

Lecture: Lecture with multimedia presentations, Lab: Independent laboratory work.

Expository teaching methods

- informative (conventional) lecture

Exploratory teaching methods

- laboratory
- observation
- experimental

Type of course

compulsory course

Prerequisites

Basic knowledge on general, organic and physical chemistry.

Course coordinators

Term 2022/23Z:

Term 2025/26Z:

Term 2023/24Z:

Term 2024/25Z:

Assessment criteria

Lecture: Exam - W1-W5, Ue
Laboratory: credit on the basis of performed laboratory exercises and reports - U1, U2, U4, U5, U6, continuous assessment of the student during classes - K1-K4.

Examination requirements:
1. Types and methods of obtaining synthetic polymers.
2. Types of copolymers.
3. Degree of polymerization, average molecular weights and polydispersity.
4. Influence of polymers structure on their properties (in solid state and in solutions).
5. Glass temperature of polymers.
6. Mark-Houwin's equation.
7. Methods of examination of the polymer properties.
8. Polymer blends and composites.
9. Modern plastics for special applications.

Practical placement

not applicable

Bibliography

List of basic literature:

J. F. Rabek, Współczesna wiedza o polimerach, PWN, Warszawa 2008.
Praca zbiorowa, Z. Florjańczyk, S. Penczek (red.), Chemia polimerów, t. I-III, Oficyna Wydawnicza Politechniki Warszawskiej, Warszawa 2006.
J. Pielichowski, A. Puszyński, Chemia polimerów, TEZA, Kraków 2004.
M. Mucha, Polimery a ekologia, Wydawnictwo Politechniki Łódzkiej, Łódź 2002.
D. Żuchowska, Polimery konstrukcyjne. Wprowadzenie do technologii i stosowania, WNT, Warszawa 2000.
H. Galina, Fizykochemia polimerów, Oficyna Wydawnicza Politechniki Rzeszowskiej, Rzeszów 1998.
L. Huppenthal, Roztwory polimerów. Wydawnictwo Uniwersytetu Mikołaja Kopernika, Toruń 2008.
S. Połowiński, Chemia fizyczna polimerów, Wydawnictwo Politechniki Łódzkiej, Łódź 2001.
T. Broniewski, J. Kapko, W. Płaczek, J. Thomalla, Metody i ocena właściwości tworzyw sztucznych, WNT, Warszawa 2000.

List of supplementary literature:

W. Przygocki, A. Włochowicz, Fizyka Polimerów, PWN, Warszawa 2001.
W. Przygocki, Metody fizyczne badań polimerów, PWN, Warszawa 1990.
D.W. Van Krevelen, Properties of Polymers, Elsevier Science Publisher, Amsterdam, Oxford, New York 1990.

Additional information

Additional information (registration calendar, class conductors, localization and schedules of classes), might be available in the USOSweb system:

Description of 0600-S1-ChK-ChP in USOSweb